Demolition Article #1 By: King Arthur The Police Station xxx-xxx-xxxx Like all chemists I must advise you all to take the greatest care and caution when you are doing this. Even if you have made this stuff before. This first article will give you information on making nitroglyerin, the basic ingredient in a lot of explosives such as straight dynamites, and geletin dynamites. --------------------------------------- Making nitroglycerin --------------------------------------- 1. Fill a 75-milliliter beaker to the 13 ml. Level with fuming red nitric acid, of 98% pure concentration. 2. Place the beaker in an ice bath and allow to cool below room temp. 3. After it has cooled, add to it three times the amount of fuming sulferic acid (99% h2so4). In other words, add to the now-cool fuming nitric acid 39 ml. Of fuming sulferic acid. When mixing any acids, always do it slowly and carefully to avoid splattering. 4. When the two are mixed, lower thier temp. By adding more ice to the bath, about 10-15 degrees centigrade. (Use a mercury-operated thermometer) 5. When the acid solution has cooled to the desired temperature, it is ready for the glycerin. The glycerin must be added in small amounts using a medicine dropper. (Read this step about 10 times!) Glycerin is added slowly and carefully (i mean careful!) Until the entire surface of the acid it covered with it. 6. This is a dangerous point since the nitration will take place as soon as the glycerin is added. The nitration will produce heat, so the solution must be kept below 30 degrees centigrade! If the solution should go above 30 degrees, immediately dump the solution into the ice bath! This will insure that it does not go off in your face! 7. For hte first ten minutes of nitration, the mixture should be gently stirred. In a normal reaction the nitroglycerin will formas a layer on top of the acid solution, while the sulferic acid will absorb the excess water. 8. After the nitration has taken place, and the nitroglycerin has formed on the top of the solution, the entire beaker should be transferred slowly and carefully to another beaker of water. When this is done the nitroglycerin will settle at the bottem so the other acids can be drained away. 9. After removing as much acid as posible without disturbing the nitroglycerin, remove the nitroglycerin with an eyedropper and place it in a bicarbonate of soda (sodium bicarbonate in case you didn't know) solution. The sodium is an alkalai and will nuetralize much of the acid remaining. This process should be repeated as much as necesarry using blue litmus paper to check for the presence of acid. The remaining acid only makes the nitroglycerin more unstable than it already is. 10. Finally! The final step is to remove the nitroglycerin from the bicarbonate. His is done with and eye- dropper, slowly and carefully. The usual test to see if nitration has been successful is to place one drop of the nitroglycerin on metal and ignite it. If it is true nitroglycerin it will burn with a clear blue flame. ** Caution ** nitro is very sensative to decomposition, heating dropping, or jarring, and may explode if left undisturbed and cool. Demoltion Article #2 By: King Arthur The Police Station xxx-xxx-xxxx I have decided to skip the article on mercury fluminate for a while and get right into the dynamite article. Dynamite is nothing more than just nitroglycerin and a stablizing agent to make it much safer to use. For the sake of saving time, I will abbreviate nitroglycerin with a plain NG. The numbers are percentages, be sure to mix these carefully and be sure to use the exact amounts. These percentages are in weight ratio, not volume. no. ingredients amount --------------------------------------- #1 NG 32 sodium nitrate 28 woodmeal 10 ammonium oxalate 29 guncotten 1 #2 NG 24 potassium nitrate 9 sodium nitate 56 woodmeal 9 ammonium oxalate 2 #3 NG 35.5 potassium nitrate 44.5 woodmeal 6 guncotton 2.5 vaseline 5.5 powdered charcoal 6 #4 NG 25 potassium nitrate 26 woodmeal 34 barium nitrate 5 starch 10 #5 NG 57 potassium nitrate 19 woodmeal 9 ammonium oxalate 12 guncotton 3 #6 NG 18 sodium nitrate 70 woodmeal 5.5 potassium chloride 4.5 chalk 2 #7 NG 26 woodmeal 40 barium nitrate 32 sodium carbonate 2 #8 NG 44 woodmeal 12 anhydrous sodium sulfate 44 #9 NG 24 potassium nitrate 32.5 woodmeal 33.5 ammonium oxalate 10 #10 NG 26 potassium nitrate 33 woodmeal 41 #11 NG 15 sodium nitrate 62.9 woodmeal 21.2 sodium carbonate .9 #12 NG 35 sodium nitrate 27 woodmeal 10 ammonium oxalate 1 #13 NG 32 potassium nitrate 27 woodmeal 10 ammonium oxalate 30 guncotton 1 #14 NG 33 woodmeal 10.3 ammonium oxalate 29 guncotton .7 potassium perchloride 27 #15 NG 40 sodium nitrate 45 woodmeal 15 #16 NG 47 starch 50 guncotton 3 #17 NG 30 sodium nitrate 22.3 woodmeal 40.5 potassium chloride 7.2 #18 NG 50 sodium nitrate 32.6 woodmeal 17 ammonium oxalate .4 #19 NG 23 potassium nitrate 27.5 woodmeal 37 ammonium oxalate 8 barium nitrate 4 calcium carbonate .5 Household equivalants for chemicles It has come to my attention that m any of these chemicles are sold under brand names, or have household equivalants. here is a list that might help you out. acetic acid vinegar aluminum oxide alumia aluminum potassium sulfate alum aluminum sulfate alum ammonium hydroxide ammonia carbon carbonate chalk calcium hypochloride bleaching powder calcium oxide lime calcium sulfate plaster of paris carbonic acid seltzer carbon tetrachloride cleaning fluid ethylene dichloride Dutch fluid ferric oxide iron rust glucose corn syrup graphite pencil lead hydrochloric acid muriatic acid hydrogen peroxide peroxide lead acetate sugar of lead lead tetrooxide red lead magnesium silicate talc magnesium sulfate Epsom salts naphthalene mothballs phenol carbolic acid potassium bicarbonate cream of tartar potassium chromium sulf. chrome alum potassium nitrate saltpeter sodium dioxide sand sodium bicarbonate baking soda sodium borate borax sodium carbonate washing soda sodium chloride salt sodium hydroxide lye sodium silicate water glass sodium sulfate glauber's salt sodium thiosulfate photographer's hypo sulferic acid battery acid sucrose cane sugar zinc chloride tinner's fluid Keep this list handy at all times. If you can't seem to get one or more of the ingredients try another one. If you still can't, you can always buy sm all amounts from your school, or maybe from various chemical companies. When you do that, be sure to say as little as possible, if during the school year, and they ask, say it's for a experement for school.